After installing the operating system, the system is unable to boot from the array.
GRUB only recognizes msdos partition tables. Since msdos partitions are limited to 2TB in size, it is not possible to directly boot from a > 2TB array.
To work around this, you can enable a feature in the 3Ware BIOS called 'autocarving'. This will split the array into multiple 2TB volumes (/dev/sda, /dev/sdb, etc). The BIOS of newer controllers also support the option to create a small boot volume (/dev/sda) and then allocate the rest of the array to a single large partition. The following 3Ware knowlegebase article has more information: